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by sigmoid10
16 days ago
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That still doesn't answer why these relativistic effects don't cause neighbouring elements to be liquid. Electron velocities should be quite similar for them. There must be something apart from relativistic effects that makes mercury special in that regard. |
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In gold it changes the color, in Mercury it changes freezing temperature.
Gallium has a low melting point 29.76C but that is due to unique chemical bonding.
"relativistic contraction" (shrinking of s and p orbitals) and "relativistic expansion" (destabilization of d and f orbitals) causes many observed phenomena.
Relativistic contraction of the 6s orbital and expansion of the 5d orbital lower the energy required to excite electrons. Consequently, gold absorbs blue light.
Strong relativistic contraction of the outer 6s electrons leaves them tightly bound and unavailable for metallic bonding. This results in incredibly weak atomic interactions, thus mercury a liquid at room temperature.
Lead also has 6s, which is what makes lead acid batteries work as well as they do.
So while the observed effects change, there are relativity effects with several nearby neighbors.