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by sigmoid10
14 days ago
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I think you still misunderstood the question. Noone asked if there are relativistic effects with neighbors. In fact, it was said at the very beginning that they certainly have these relativistic effects too. The actual question is why are gold/thallium/cadmium etc. not liquid. There must be something apart from relativistic effects that explains why mercury turns into liquid at room temperature and these others don't. |
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And here come the relativistic effects, which essentially scale with nuclear charge of the nucleus come to play and they are significantly stronger for Hg than Cd. If I remember correctly (although I read about it a long time ago so I may be a bit rusty) these strong relativistic effects cause something called "relativistic contraction of the 6s orbital" which results in the electrons on this orbital being more strongly bound than they would be, if there would be no relativistic effects (which can be theoretically compared by setting c -> infinity in the equations used to solve electronic structure theory). AFAIR Copernicium should also be liquid in room temperature for similar reasons, but since it is not very long lived and it is difficult to produce testing this will likely be very hard if not impossible to check (though if I remember correctly there was something called "relativistic maximum" which happens in the 6th and not 7th row of periodic table for some reason, so it should be higher than for mercury; though I can't remember the details why this is so).
Of course this is a bit simplified picture and there are surely more details regarding how exactly relativistic effects influence the energies and consequently how this influences the melting temperature of mercury (I suppose they are in the Calvo, Pahl, Wormit and Schwerdtfeger paper linked earlier in this thread), but I think the combination of the electron configuration and strong relativistic effects explain why other neighbors are not liquid.