| > You seem to think you made progress on us agreeing that entropy is a "model. I thought we had agreed that entropy is something you calculate with a model, in fact. > You're implying that there is some input parameter modeled after knowledge. I was trying to say that the inputs to S(...) are the things that we know because we did measure them or set their values. It seems that we agree on that because it's extremely obvious. Hopefully we also agree that if there are other other relevant things that we know in addition to the inputs to that model we could refine our model. I fully acknowledge that we may choose to ignore the additional knowledge and keep using the old model - and it may be good enough for some uses. (We may also choose to incorporate the additional knowledge. Maybe it rules out some microstates and we could be using a smaller macroset to represent what we know about the system.) When all we know is the macrostate, the macrostate is the most detailed description - and gives the most precise predicitions - available to us regarding the system. However, if we know more the original macrostate is no longer "complete". Because we do know - and we can predict - more precise things. There is a fundamental change from "the macrostate represents all we know and is the basis of everything we can predict" to "not the case anymore". Which also seems obvious. Probably we agree on that as well! (Sure, it applies to everything. Anytime one ignores information one has a suboptimal model compared to the model one could have. The improved model may or may not be better for a particular purpose.) > Who says you can add these two entropies together? S1 and S2. Alice, who considers two equal volumes of an ideal gas at the same temperature and pressure. > The macrostates are different They were the same in my example. Same volume. Same temperature. Same pressure. > and Mixing the two gases likely produces a third unique set of macrostates indpendent of the initial two For an ideal gas doubling the volume and the number of particules (so the pressure remains the same for a fixed temperature) doubles the entropy. If you have two identical systems the total entropy doesn't change when you put together the two containers resulting in a single container twice as large with twice as many particles. If you thought that the number of microstates - and the entropy - increases when you bring toghether two identical systems because they will mix with each other that's not correct. (Even though there are still debates about this issue 120 years later.) https://en.wikipedia.org/wiki/Gibbs_paradox The entropy would increase however if they are different ideal gases (it doesn't matter how different). Bob - who knows that they are different - would calculate the correct entropy. It could be the other way. Maybe they're actually the same gas but Bob treats them as different because he isn't aware and keeps the general case. He calculates an increase in entropy due to the mixing. While for Alice, who knows that they are the same gas, the total entropy hasn't changed. Ax Maxwell wrote: "Now, when we say that two gases are the same, we mean that we cannot separate the one from the other by any known reaction. It is not probable, but it is possible, that two gases derived from different sources but hitherto regarded to be the same, may hereafter be found to be different, and that a method be discovered for separating them by a reversible process." If we think that the two gases are the same the entropy is 2S but if we discover later a way to tell apart one from the other the entropy is higher (there are more microstates for the same macrostate that we thought initially). |
We did agree. I never said otherwise. Where are you getting this idea? I'm saying our agreement on this fact is useless. Why don't you actually fully read what I wrote.
>I was trying to say that the inputs to S(...) are the things that we know because we did measure them or set their values. It seems that we agree on that because it's extremely obvious.
I spent paragraphs remarking on this ALREADY. I get what your saying. You're not even reading what I wrote. Every mathematical model has this property you describe. It is not unique to entropy. If you don't know the parameters of even the Pythagorean theorem, then you can't calculate the length of the hypotenuse. Does this mean the pythagorean theorem depends on your knowledge of the system? Yes but kind of a pointless thing right? If this is the point your trying to make, which I highly doubt, then why are we focusing only on entropy? Because knowledge of any system is REQUIRED for every single mathematical model that exists or the model is useless.
I don't think your clear about the argument either. If your not talking about knowledge as a quantifiable input parameter then I don't think your clear about what's going on.
>I fully acknowledge that we may choose to ignore the additional knowledge and keep using the old model - and it may be good enough for some uses.
Entropy is used with full knowledge that it's an fuzzy model. It's based on probability. It doesn't matter if we "ignore" or don't know the additional properties of the model. The model doesn't incorporate that data regardless of whether that information is known or not known.
>They were the same in my example. Same volume. Same temperature. Same pressure.
No. The boltzman distribution changes with gas type as well. The models are different.
>For an ideal gas doubling the volume and the number of particules
In this case yes. But only for an ideal gas. I don't recall if you mentioned the gases were both ideal. Let me check. You did mention it. But then you mention the gases are different. Hydrogen and helium. Neither gas is technically ideal, and the quantum mechanical effects would likely influence the boltzman distribution when mixed. There are contradictions in your example that make it not clear.
>https://en.wikipedia.org/wiki/Gibbs_paradox
The article you linked explains it away. It's the choice of Macrostates, effects the entropy outcome. The article says it's subjective in the sense that it's your choice of Macrostates. The Macrostates don't change based off your knowledge. You choose the one you want.