The element inspector comes somewhat close, but you can't add css attributes to selectors, only modify existing ones, which really makes the thing useless when doing front end dev
unless you're seeing something I'm not seeing, you can only modify existing attributes. If you could show me though, an upvote will be in your future :-)
Though not as useful as firebug you are able to add a 'style="<custom css>"' attribute to an element by hovering over and clicking the '?=""' that appears.