Hacker News new | ask | show | jobs
by cmatteri 4262 days ago
The use of leaded paint indoors and of leaded gasoline were particularly dangerous, but there are still numerous potential sources of lead exposure, especially in certain industries, but also for the average person. Exposure has decreased, but the safe blood lead level has also been reduced as we become increasingly aware of the harms of sub-clinical lead poisoning.

Two interesting properties of lead's toxicity that weren't mentioned in the article are its potency and its ability to accumulate. A blood lead level of 10 ug/dL is often listed as a threshold for concern (though for children 5 ug/dL or less is more appropriate). A typical blood volume for an adult is around 50 dL (according to Wikipedia), so 10 ug/dL would mean that there are 500 ug of lead in your blood. Lead has a density of 11.3 g/cm^3, so 500 ug has a volume of 44.2 nL. If you have every used a 2 uL pipette, you would have an idea of how small of a volume 44.2 nL is (for those who haven't, it's somewhere in the range of a grain of sand http://en.wikipedia.org/wiki/Orders_of_magnitude_%28volume%2...). Although not all the lead we ingest is absorbed and lead is distributed throughout various organs, this should give a sense of how potent of a toxin lead is. Lead is also cleared from the body fairly slowly, so the amount of exposure per day needed to build up to a toxic level is even lower. These two properties, combined with the ubiquity of lead in our society, the long timescales over which it causes harm, and widespread ignorance of or apathy towards its harms are why I find it a particularly frightening toxin.

One source that could be relevant to some in the HN crowd is electronics solder. Although Europe banned the use of lead in electronic components and solder in most applications in 2006 with RoHS, leaded solder is still mostly legal and common in the US (it looks like CA has partially adopted RoHS http://en.wikipedia.org/wiki/Restriction_of_Hazardous_Substa...). It is fairly easy to use leaded hand solder safely, but it is also entirely plausible that a child with inadequate training or supervision could ingest a significant amount of lead while soldering, from the small flakes of solder that accumulate on your workbench, dust, or lead oxides on a sponge. I had no idea how toxic lead was when I taught myself to solder in high school, and I'm glad I didn't do it much then for that reason.

I have recently started using Sn96.5Ag3Cu0.5 (lead free) solder, and although it is somewhat more expensive that leaded solder, with proper tools, plated PCBs, and correct technique it is really quite easy to use. I have some aggressive rosin-activated flux on hand (that requires cleanup) but I haven't needed to use it so far. I would highly recommend trying out Sn96.5Ag3Cu0.5, especially if you're sharing a workspace with children, who are far more susceptible to lead for various reasons.

A fair number of materials that you might encounter can contain lead as an additive, including plastic, brass, bronze, steel (http://en.wikipedia.org/wiki/Free_machining_steel), and metal/hobby/industrial/artist paints. It's always worth looking up what hazardous compounds may be present in something before putting a grinder to it (again, something I hadn't mastered in high school).

More along the lines of the article, here is another particularly egregious historical use of lead as a color in candy. In this case the compound, lead (II) chromate, also contained hexavalent chromium, another particularly hazardous chemical (http://books.google.co.uk/books?id=aC9NAAAAMAAJ&pg=PA93&dq=%...).

2 comments

Beyond the sibling comments about the flux being the nasty part of solder, and the part in solder fumes that are hard to avoid breathing at least a bit of when soldering, eutectic leaded solder is soo much nicer to use than the lead-free stuff. It melts at a lower temperature, and melts/hardens all at once, making it dramatically easier to avoid bad solder joints. In particular, lead-free solder will really make you despise a cheap soldering iron.

But yeah, be careful and don’t eat solder flakes, and wash hands after soldering.

From what I was told, lead-free solder has a large amount of flux in it to make it half-way usable. Unless you're licking your fingers after soldering with leaded solder, you may be doing more damage to your lungs with the lead-free stuff than you're doing to your body with the leaded. But I'd love to see the numbers on this.
I've looked into this, but I'm torn. In my mind the most compelling arguments against lead-free are: of the studies of factory workers who work every day with lead/tin solder, they couldn't find elevated blood lead levels; and that the fluxes in lead-free solders are both more exotic (i.e. less studied for adverse health effects) and a greater proportion of the solder.

The danger of absorbed lead is clear, but it's not a straight line from there to lead-free solder. Furthermore, the process that resulted in the EU (mostly) banning lead solder seems to be based more on the precautionary principle than any evidence of health or environmental damage from solder specifically. Added to that is some definite PR misinformation floating around - it's been hard for me to come to any conclusions.

The EU regulation is about preventing lead contamination of the waste stream.
I believe it contains on the order of twice as much flux, but I can't find a source for that at the moment. So I don't think flux fumes are much more of a concern than with leaded solder (for which you should have good ventilation or a fan). I did have a ball of solder shoot towards me when I was first getting a feel for it, so you definitely need safety glasses, though I understand this can occur with leaded solder as well, and you want to wear glasses anyways to keep clipped leads out of your eyes.