[sparkie]

I liked Terra e (2007, not the 1980 film which isn't very good). It bears some similarities to Psycho-Pass, although it probably doesn't meet the "mature" marker with its super powers.

I struggle to recommend more because mature anime is almost nonexistent these days. I can count on one hand the number of shows that might fit the bill in the past 5 years (Aoi Bungaku, Jormungand, Attack on Titan and Night Raid perhaps, and they're not all good).

If you just want something entertaining without the same old cliches in most anime, then Gintama will have you in stitches.