I'd say learn how CSS works first and really understand what it's doing. However, Sass can help you write very maintainable efficient styled code.
I will always recommend using Sass, but only if you know what CSS you're making and know that it matters what CSS is being output.
In practice however, the generated output isn't always the best, and it's worth a look over to make sure it's not generating slower selectors.
I'd say learn how CSS works first and really understand what it's doing. However, Sass can help you write very maintainable efficient styled code.
I will always recommend using Sass, but only if you know what CSS you're making and know that it matters what CSS is being output.