[jpmattia]

> The problem is with carbon in general is it has a band gap 5x larger then Silicon. Which overall (but not entirely) means if you want to build a transistor with Diamond (or graphene) you need to put 5x as much voltage into it.

I should have said electron affinity rather than electronegativity: You're not trying to get electrons from the valence band into the vacuum, just from the conduction band to the vacuum. Diamond actually has a negative electron affinity, which is why the vacuum electronic folks were excited about it.