For one thing, the use among civilian populations of white phosphorus as a weapon (rather than as part of a smoke screen) is of dubious legality; seehttp://en.wikipedia.org/wiki/White_phosphorus
I think the legality is pretty clear. Protocol III of the Concentional Weapons Convention bans incendiaries under many circumstances, but the US has not adopted it.
http://en.wikipedia.org/wiki/Convention_on_Certain_Conventio...
http://www.icrc.org/ihl.nsf/NORM/C1C4BFCF736BF820C1256402003...
Some activists also wish to call it a chemical weapon, but by that logic lead bullets are also a chemical weapon (since lead is toxic).