Never knew, do you a have a source on this? Not that I don't believe you, I just want to read more about it. A Chrome extension that shows you if STARTTLS is being used would be really neat.
Source: Me, who runs (among other things) mail servers for an ISP.
ETA:
Received: from mail-pd0-f169.google.com (mail-pd0-f169.google.com [209.85.192.169])
(using TLSv1 with cipher RC4-SHA (128/128 bits))
(No client certificate requested)
by MAIL.MYDOMAIN.COM (Postfix) with ESMTPS id 1BBFA2909
for <ME@MYDOMAIN.COM>; Thu, 23 Jan 2014 23:00:32 -0500 (EST)
ETA: