Perfect forward secrecy would prevent some attacks against Google, as does certificate pinning in Chrome. But if the NSA got somehow Google's secret key, they can still MITM a SSL connection. It just means, that they actually need Google's secret key, instead of using a CA under their control. ( And they need this key before they can MITM any connection.)
And the entire secure connection stuff is broken, if the NSA just obtains a FISA warrant for your GMail account. ( Or compromises the Google servers directly.)
What PFS will protect against in this scanario is decrypting SSL sessions whose cyphertexts were captured before the attacker had access to the private key. It doesn't protect against (any) man-in-the-middle attacks.
Before or after they have access to the private key, so long as an active MITM is not performed. In essence, PFS makes it such that no matter what information you have about the server's configuration, passive sniffing of data is not enough to compromise a connection's confidentiality.