It actually wouldn't, because the entropy doesn't rely on the attacker not knowing the general format - it relies on the number of words available as choices.
English has roughly 100,000 words, so that password scheme has 10^15 combinations. Suppose the latter scheme incorporates the 96 printable Ascii characters. log96(10^15) is 7.5, so yes the latter scheme gets ahead on entropy at 8 characters or longer.
But it's not a question of maximizing entropy. It's a question of maximizing entropy relative to the human brain's ability to remember it. The brain handles words as single units, so it's a lot easier to remember three of them than eight or more arbitrary characters.
Doesn't the entropy just measure the difficulty of brute forcing a password though? From an entropy perspective, "password" may be more secure than "r&E2pX@", but I doubt anyone attempting to crack passwords in a practical manner is going to adopt a direct brute force approach.
But it's not a question of maximizing entropy. It's a question of maximizing entropy relative to the human brain's ability to remember it. The brain handles words as single units, so it's a lot easier to remember three of them than eight or more arbitrary characters.