I dont' know Python but I'm thinking about learning it. What's experimental about Python 3? I don't have any legacy reasons to start with 2.7. Why wouldn't I just start with 3?
there's nothing experimental about Python 3. its a stable release version and I think its already up to sub version 3.3.
HOWEVER, there are many important 3rd party libraries that have not yet been migrated to be fully compatible with Python 3. these libraries are far more important to writing real applications than the ability to use some newer syntactic constructs in Python 3.
South (database migration for django). Until django core has its own migration tool I won't be using it with Python 3.
PIL as well. similar reasons. django image fields are dependent on PIL.
Celery is still on Python 2 also, and while there are other message queues available, none of them is as easy to integrate with for an app that's already written in Python.