[mistercheph]

Briefly: education is concerned with thinking, vocational training is concerned with task performance. There are lots of synergies and gray areas between the two, e.g. certain kinds of task proficiency are really helpful tools while thinking (e.g. arithmetic), and thinking is a really helpful tool while task performing (e.g. an unseen permutation of a task)

That question probably deserves a much longer, more complete answer than this, but another poor imprecise framework is that education empowers people to tackle new problems poorly and taking lots of time, vocational training empowers people to tackle existing problems with known solutions excellently. In the language of the greeks, nous and techne.