The same as P4 rev 3.x, which is still undocumented. Assembler source and esp-nn/esp-dsp are your friend. Some people have also tried some stuff.
And HP core 0 is scalar-only now.
For compatibility and simplicity. Most SIMD instructions in P4 and S31 (compatible with P4 rev 3.x) are an direct evolution from S3. Espressif just doesn't want to rewrite their optimized assembly libraries.
But with the weird alignment thing fixed