At least some ISS astronauts describe smelling burnt metal after returning from EVA, if memory serves. (Others may smell ozone, I've just always remembered hearing burnt metal).
the exterior of the ISS is constantly exposed to small mounts of atomic oxygen, which is an incredibly strong oxidizer. probably in addition to ozone there is a huge variety of organic and inorganic oxides that get tracked in through the airlock.
Fun trivia (well, perhaps not fun) in the second paragraph: "the Long Duration Exposure Facility (LDEF), which was retrieved in 1990 after spending 68 months in LEO"
Long exposure, 68 months, right. But it was only supposed to be in orbit for 11! Challenger being destroyed on reentry made a mess of things.
>It was placed in low Earth orbit by Space Shuttle Challenger in April 1984. [...] At LDEF's launch, retrieval was scheduled for March 19, 1985, eleven months after deployment.[4] Schedules slipped, postponing the retrieval mission first to 1986, then indefinitely due to the Challenger disaster. After 5.7 years its orbit had decayed to about 175 nautical miles (324 km) and it was likely to burn up on reentry in a little over a month.[6][9]: 15
They say that about vaccum. eg. an airlock after re-pressurising it after a spacewalk. Apparently a vaccum sucks stuff like sulphur from within steel to it's surface.
https://en.wikipedia.org/wiki/Materials_International_Space_...