Can you share details on how one trivially connects via IPv6 only? I see no option in iOS Wi-Fi settings to do this, and I think it's reasonable to expect not to have to turn off IPv4 on my access point to test IPv6-only networking.
I’m going to guess no one responding to me has actually tried connecting to an IPv6 only network because it works without incident. Will your apps? Who knows - apple hasn’t always been great at enforcing that.