The tool chains that Espressif seem to work pretty well with these as well as their earlier (some sort of RISC) processors. I have had some code, however, that did not produce desired results until I upgraded the toolchain.
The other issue I've run into is that some cell phone battery packs that work well with Raspberry Pis won't stay on with the RISC-V ESPs because they draw so little power the battery pack doesn't detect the load.