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by srean
394 days ago
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In Boltzmann's formulation of stat-mech it comes from the assumption that when a system is in "equilibrium", then all the micro-states that are consistent with the macro-state are equally occupied. That's the basis of the theory. A prime mover is thermal agitation. It can be circular if one defines equilibrium to be that situation when all the micro-states are equally occupied. One way out is to define equilibrium in temporal terms - when the macro-states are not changing with time. |
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