I am not a hammerer. Yet once when I saw PL/SQL on a candidate's resume, I did start asking some questions--not stuff like "explain PRAGMA WNDS" but "tell me a bit about how you've done xyz in PL/SQL" and promptly hit a blank look.
I think that it is reasonable to ask questions about what is on a resume.
I think that it is reasonable to ask questions about what is on a resume.