No, but for verifying equivalence you could use some symbolic approach that is provably correct. The LLM could help there by making its output verifiable.
Program equivalence is undecidable, in general, but also in practice (in my experience) most interesting cases quickly escalate to require an unreasonable amount of compute. Personally, I think it is easier to produce correct-by-construction decompilation by applying sequences of known-correct transformations, rather than trying to reconstruct correctness a posteriori. So perhaps the LLM could produce such sequence of transforms rather than outputting the final decompiled program only.