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by rejuvenile 5082 days ago
I used to make aerogels (a related class of materials) in high school; allow me to give a (hopefully accurate) layperson's overview.

Aerogels formerly held the record for least dense solid. They're not gels, but they're called aerogels because they're made from gels. As the name "aero" implies, they're mostly air, giving them incredible strength-to-weight ratios and insulating properties. Silica aerogels are translucent and quite amazing to hold; it's like holding a cloud.

Aerogels are made from colloids (a.k.a. gels), which are long chains of polymers formed in water. Free-floating around in the water, they form very long, intricate, 3-D maze-like structures. If you've ever made JELL-O, you've made (and eaten) a colloid. It’s the intricate structure of the colloid which keeps the suspended water from spilling out.

Silica aerogels are formed by removing the water from a silica gel, leaving only the maze like structure behind. This structure is very delicate, and if you attempt to evaporate the water out near room temperature/pressure, the capillary action of water will collapse the structure like a dried out jellyfish. However, if you heat and pressurize the system past the critical point, the water becomes a supercritical liquid and it can be removed without pulling the rest of the material inwards.

It appears that what they’ve done here is similar, except they use a multi-step process to deposit carbon on the colloid, then remove the colloid completely, leaving nothing but a carbon maze. I presume they can't make colloids out of carbon directly, hence the multistep process.

2 comments

I want to emphasize how strange a piece of aerogel is to hold. The aerogel fragments I've seen were cylindrical, and looked exactly like bits of hot glue sticks. However, it feels nothing like a hot glue stick. Touching this particular aerogel was like touching a lighter, fluffier, finer grained version of styrofoam, almost like the cotton candy to styrofoam's unleavened bread. The aerogel is also ridiculously low-mass, so it seems to require no effort to hold or move around. It's something that must be experienced.
What an awesome hobby that must be! I'd be inclined to try it if I weren't sure I'd kill myself with chemistry.
I am certain it's easier than you are imagining. Try it!
that reminds me of the (thankfully!) small hydrogen explosion I set off in my parents' basement when I was in High School. I was trying to make a hydrogen-powered bunsen burner. I blew up my prototype but no other damage (the prototype was powered by a magnesium-vinegar hydrogen gas generator).