Legally speaking, once they own the copyright, is there anything stopping the PSF from selling out and changing their policy to permit proprietary licensing?
I have this same concern with GNU. I can imagine a future where some key figures have died or retired and the new org sells out and changes the license to something RMS never would have agreed to.
To go along with the other response, they don't own your copyright -- but I don't know if the language in the Python CLA actually holds them to the "we can only relicense to open source licenses" if challenged in a court.
But that's not really a risk I care about. The PSF is a nonprofit that's clearly aimed at being a nonprofit, and a Future Evil Board is beyond what I'm going to worry about.
I have this same concern with GNU. I can imagine a future where some key figures have died or retired and the new org sells out and changes the license to something RMS never would have agreed to.