I believe the benefit to Tai Chi is that you're more in motion.
With Yoga you are more static. If you are static in a position where your muscles are contracted, it's hard to relax.
With Tai Chi you are doing movements which contract and relax your muscles for shorter periods of time, which helps you relax. Also, the fluid movements can bring you to a state of effortlessness, which is of course also relaxing.
With Tai Chi you are doing movements which contract and relax your muscles for shorter periods of time, which helps you relax. Also, the fluid movements can bring you to a state of effortlessness, which is of course also relaxing.