If you have anything at all to do with OS administration, management, or software packaging, it's worth it.
If I could offer a little advice: The systemd man pages are useful as a reference, but are terrible to learn from. Part of this is because there are parts of systemd that everyone uses, and there are parts that almost nobody uses and it's hard to guess which these are at first. Also, the man pages are dry and long and quite often fail to describe things in a way that would make any sense whatsoever to someone who isn't already intimately familiar with systemd.
Most of my systemd learning came from random blog articles and of course the excellent Arch wiki.
If I could offer a little advice: The systemd man pages are useful as a reference, but are terrible to learn from. Part of this is because there are parts of systemd that everyone uses, and there are parts that almost nobody uses and it's hard to guess which these are at first. Also, the man pages are dry and long and quite often fail to describe things in a way that would make any sense whatsoever to someone who isn't already intimately familiar with systemd.
Most of my systemd learning came from random blog articles and of course the excellent Arch wiki.