They had 4 days of air
When they launched. At $250k, they probably had some drinks on board for a 24 hour trip, and 3 days of no water is considered survivable. So air is most likely the limiting factor, but it's possible they messed up the drink provisions extremely badly.
In a well-designed submersible that goes through thorough testing and gets a classification and rating... which I gather the CEO took short-cuts on. He's one of the passengers on board.