That’s not all what CA means in standard usage. Terms like WebPKI exist specifically to make that distinction since, for example, the U.S. government runs its own certificate authorities which are trusted by millions of clients and even some mainstream software (Adobe) but not browsers. This is far from unique as far as governments go, and in some cases may even be required within a country.
If your threat model includes nation-states then DNSSEC won't help you either. WebPKI at least has a method for keeping track of and detecting misissuance, DNSSEC doesn't.