People talk most about CO2 because it has the most total effect as a driver of climate change. CH4 for example has a greater effect per kilogram, but we emit a lot less of it and it doesn't last nearly as long.
H2O technically affects the temperature even more than CO2 but it's not a driver, because the total H2O in the atmosphere depends on overall temperature. Emitting more H2O, from hydrogen cars or something, would just mean you get more rain somewhere.
Maybe most sensible approach: use SRM to reduce temperature directly and head off nasty positive feedbacks like melting permafrost, but treat that as buying time to get CO2 down to a safe level.
H2O technically affects the temperature even more than CO2 but it's not a driver, because the total H2O in the atmosphere depends on overall temperature. Emitting more H2O, from hydrogen cars or something, would just mean you get more rain somewhere.