Fun and somewhat related fact - this is one of the main advantages of hollow-core transmission fibers! As far as I know, currently only used to extend the range of HFT orgs...
Hollow core fiber? Total internal reflection requires the core to be a higher index of refraction than the cladding, so I wonder how that works!
Turns out, it functions differently. Instead of total internal refraction it has to rely on weird physics like photonic crystals. The pictures are absolutely wild.