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by jxf 1294 days ago
The "notorious polysulfide shuttling effect" mentioned in the first sentence of the abstract is a pretty big understatement. It's basically an automatic death sentence for Li-S batteries in commercial applications, so the fact that this paper claims to have _zero_ polysulfide formation is pretty remarkable.

Short primer: The polysulfide shuttling effect is a phenomenon that can occur in lithium-sulfur batteries. It occurs when polysulfide ions, which are intermediates formed during the discharge and charging of the battery, are able to move from the cathode to the anode. This causes a decrease in the overall capacity of the battery.

To prevent this from happening, a separator with a high ionic resistance is used to physically block the movement of the polysulfides, but this increases the bulk and form factor of the battery, which makes it less suitable for applications like phones and laptops.