[MatteoFrigo]

I actually went down this path about 25 years ago, and I learned the hard way that CO2 hides in organic materials in a way that mostly invalidates the calibration.

I had a semi-sophisticated device consisting of a lightweight plastic cylinder that could move up and down when filled with gas, and a way to know the volume with accuracy (single-digit milliliter error out of five liters). I had a tank of pure CO2 and an air intake, coupled with valves that let me fill the cylinder with any desired mixture of CO2 and air. I wrote an automatic program that created a calibration curve in various proportions (100ppm CO2, 200ppm CO2, ..., up to 5000ppm) and collected the sensor value.

The results of this procedure made no sense, because the sensor reading collected during the calibration, e.g. at 1000ppm, was totally different from the sensor reading in response to a 1000ppm concentration created outside the calibration loop. After several days of investigation, it turned out that the problem was that I was using tubes of some carbon-based plastic material. Somehow the CO2 mixes with the plastic and is slowly released afterwards, altering the mixture. Everything worked fine after I replaced the tubes with silicon-based silicone tubes.