One could make that case, but 4th allows for searches with a warrant
I would say 5th because divulging the contents of ones mind is testimony which one should not be compelled to do, the 5th profits you from being a witness against yourself, reveling a password is being a witness against yourself
Fifth: the password is testimony. It's searching their things, but the warrant issued by the court means that it's likely a reasonable search (ergo, not a violation of the 4th).
I would say 5th because divulging the contents of ones mind is testimony which one should not be compelled to do, the 5th profits you from being a witness against yourself, reveling a password is being a witness against yourself