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This question has led me away from big box stores and more to online clothes retailers. Certain brands give a really comprehensive breakdown of what their clothes are made of and how they're constructed. Right now I'm thinking of a pair of Outlier pants that I've had for about 4 years or more by now, probably have 500 wears in them. They have some minor fading and a couple of burn holes from standing too close to campfires, but are otherwise unscathed. They were something like $150 when I bought them but I was sold on the textile they used (very durable high-nylon synth blend), and in this case it paid off -- I would have blown holes in the knees of jeans 5 times over in the same period.