That's complicated based on workload, etc. A single PG node will obviously never scale to Google or Facebook levels.
Attend a PG conference and you will run into plenty of people running PG with similar use cases(and maybe similar loads) to you.
I can say we run a few hundred concurrent users backed by PG on a small to medium sized VPS without issues. Our DB is in the 3 digit GB range on disk, but not yet TB range.
You can get a 60TB NVMe instance with 96 cores these days - https://aws.amazon.com/ec2/instance-types/i3en/. Relational databases just scream on the dang things.
> 2 million random IOPS at 4 KB block sizes and up to 16 GB/s of sequential disk throughput