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by wrycoder 1683 days ago
The BBC article is referring to high purity quartz, not silicon. It is used to make a quartz crucible - a large cup - of that high purity quartz. It’s essential that the crucible not contaminate the polysilicon.

(A note in passing: the semi industry doesn’t use hyperpure silicon. They use a lesser grade and add epitaxial layers.)

The crucible can stand the high temperature of molten silicon. The purified polycrystalline silicon is melted in the crucible. Then a single crystal ‘seed’ is dipped in the molten silicon and slowly withdrawn, while rotating. That’s how you make a high purity single crystal silicon ingot.

Before it’s zone refined, the poly is synthesized by reducing high purity silane gas (SiH4), which was in turn produced from quartz sand.

It would be interesting to know if the industry is still using natural quartz crucibles - the latest wafer size is now 450 mm - nearly 18 inches. Maybe someone else here can comment whether the traditional pulling process will be used at 450 mm.

1 comments

You are right I mixed up silica and silicon my mistake. I found the wired article thats now paywalled and I mixed those two up. https://web.archive.org/web/20180808115837/https://www.wired...

>It would be interesting to know if the industry is still using natural quartz crucibles - the latest wafer size is now 450 mm - nearly 18 inches. Maybe someone else here can comment whether the traditional pulling process will be used at 450 mm.

Is that why they're round even though chips are square? Are the round parts thrown away or do they use them somehow? Reminds me of chicago style thin crust. https://en.wikipedia.org/wiki/Chicago-style_pizza#Thin-crust...

I had not heard of Spruce Pine - thanks for the references! In the very interesting Wired article you linked, I notice that the quartz goes to GE, which spins it into crucibles. So, I guess the size is unlimited.

The current silicon ingots are amazing - cylinders a foot and a half in diameter and maybe six feet long. They are handled with cranes.

The ingots are so large and the chips so small that there isn’t much waste. The edges are often used for test patterns.

The chips don’t have to be rectangular, but it’s easier, because they are separated with diamond saws or wire saws, which cut straight lines.

Some companies make photosensors in weird shapes using ultrasonic cutters.

Even the traditional disco cutters are probably worth their own book
the smaller the heavier :)