NYC has the most stations, 424.
Shanghai has the most track, 743 km, and the most annual riders, 2834.69m.
Ask a New Yorker, and the NYC subway is the greatest in the world (oh and PATH is not part of the subway system, cuz it's not MTA and goes to New Jersey).
Also, NYC itself is the greatest city on the world. ;-)
A single ring line would in my view count as smaller than a more traditional "flared out" system, assuming they moved the same amount of passengers.
Maybe a complexity factor based on number of distinct tunnels multiplied by number of riders? Hmmm, metrics are hard...