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by tadfisher 1807 days ago
Battery swaps could be viable, barring some complications in gate infrastructure and airframe design. Obviously this would be impossible if airframe designers incorporate battery cells in structural members, as some suggest to offset the weight penalty.
3 comments

I've said for a while that electric planes are the perfect use case for aluminum-air batteries. Aluminum-air batteries have up to 8x the energy density of lithium ion, but are not rechargeable, so using them only makes sense if you have a system to recycle the used batteries. This doesn't make a ton of sense with cars, because cars are constantly going from random place to random place, and having to include a stop at a battery recycling center every ~1000km or whatever would be impractical.

But planes go between very limited sets of known points, with huge amounts of infrastructure. Adding in the capability to do Al-air battery swaps / recycling would be easy, and the benefits for the use case (huge weight savings, faster turnaround times by swapping vs charging) are big.

Apparently Eviation is looking into aluminium air batteries https://en.wikipedia.org/wiki/Eviation_Alice
Small tertiary airports often served by short regional flights don't have a lot of infrastructure. They have a couple of fuel trucks and a gate agent/security screener/baggage handler who might all be the same person.
So instead of a fuel truck you have a battery swapper.

You'll have to ship the batteries somewhere they can charge/reprocess, but you also need to ship fuel, so it's a 1-to-1 tradeoff (you can ship the batteries by land).

Is it 1:1? There are a lot more KWh in a tanker truckload of jet fuel than in the same volume of batteries.
Not that much more (theoretically) - Al-air batteries could reach up to ~8kWh/kg, which is in the same range as jet fuel's 12ish. Aluminum is also denser than jet fuel, so per unit volume it could be even closer.
What's the process for recycling an aluminum-air battery? And is it cost/energy effective to do so?

(If you think about it, closed-loop recycling of energy storage is just another form of recharging, but with extra steps.)

From wikipedia[0] "it is possible to mechanically recharge the battery with new aluminium anodes made from recycling the hydrated aluminium oxide". I've found a few papers regarding recovery of aluminum from aluminum oxides, but I don't have the background to interpret them with an eye towards that process's impact on the overall efficiency of the battery.

[0] https://en.wikipedia.org/wiki/Aluminium–air_battery

Production of aluminum metal from aluminum oxide is hugely energy-intensive. Aluminum plants often have an on-site utility-size power plant to provide the electricity. Is this same energy needed to recycle the oxide from the batteries? If so it seems like a non-starter, maybe unless it could be done with solar generation.
> Is this same energy needed to recycle the oxide from the batteries?

The energy delivered by the battery in flight, is what you need to use to restore it back to fresh. The more energy you need the better your battery.

Why does it need to be specifically solar? Use electric from the grid, and as the entire grid changes over to other power sources so will this.

The real question here is the ratio of energy delivered over the life of a fresh anode as it is fully converted to aluminum oxide, to the amount of energy required to turn that same aluminum oxide back into a pure aluminum anode.
> Why does it need to be specifically solar? Use electric from the grid,

The vast majority of grid electricity is still produced from fossil fuels (at least where I live).

There is no "recharging" an aluminum-air battery, you add the energy back through recycling (smelting) it.

One of the big synergies is with renewables: With the right industrial process, you can treat this smelting process as a way to dump excess energy in peak production times.

It's the same idea of green hydrogen. Only hydrogen allows you to use pipelines instead of physically hauling everything. You also don't have to worry about the battery physically gaining weight as you fly.
I remember 20 years back, hydrogen was going to be it. There were prototype cars manufactured, calls for hydrogen fueling stations to be built, everyone scrambling to get on the hydrogen train. Then it all just fizzled out. It was probably one of the promised techs I most wish had lived up to the hype.
It's going to live up to the hype. It just didn't happen in that timeframe.
Doesn't smelting generate a ton of waste heat, though? Sounds like a process that uses far more energy than the aluminum-air battery can hold.
Because aluminum-air batteries are not rechargeable, they're fundamentally inferior to hydrogen fuel cells (which work in nearly the same way!). At least with hydrogen you can refuel the airplanes with a liquid instead of having to use a physical battery swap. Also, even higher energy density that doesn't gain weight during flight.
The "more info" page on their website says they are ruling out battery swaps, at least for now, since a battery swap would require a mechanical certification every time it was done.

They are swappable though: they explain that used battery packs can be replaced and that used packs can be used for a second purpose with less stringent requirements. For example, an energy storage facility at the airport.

"Obviously this would be impossible if airframe designers incorporate battery cells in structural members, as some suggest to offset the weight penalty."

Why not do both?

Swap one part and charge just the internal batteries. But internal batteries does not sound so clever with limited lifetime anyway.

Charging is limited by two factors:

- the power you can get from the charger to the batteries - the power the cells can accept

You can reasonably easily fix the first point with custom infrastructure, so the second point will be the limiting factor, and that one means that it always takes e.g. 20 minutes to charge your batteries, regardless how many you're charging (because with a bigger battery, you're simply charging more cells in parallel, at the same speed per cell).

I've always wondered about this, do electric cars charge each cell in parallel? or are there some series connections?