[mytailorisrich]

Depending on the species it may make sense to raise the humidity in the air (that's especially valid for indoor plants or tropical plants in greenhouses, hence misting). But watering the leaves is not needed and is pretty much useless to the plant. In nature of course plants get wet under the rain but, as mentioned, this helps diseases (moulds, mildew, virii, etc) take hold so in general it's best avoided if at all possible.