That's a massively complicated endeavor and would require a lot of knowledge we don't have at the moment principally zero G mining and remote robotic assembly (time lags will mean it'll have to be very automated).
The faster you can accelerate them the more dV you get out of each chunk so you want to get them moving as fast as possible. If you're barely tossing them off the asteroid you might need to throw away a majority of the asteroid's mass to move it into Earth's orbit.