(see https://docs.python.org/3/c-api/init.html#releasing-the-gil-... in the Python C API manual).
That's only called from the ERRWRAP2 macro here: https://github.com/opencv/opencv/blob/4.5.0/modules/python/s...
That macro, in turn, is called from gen_template_func_body in gen2.py: https://github.com/opencv/opencv/blob/4.5.0/modules/python/s...
And that seems to be a code generator that is generating the bindings for all the OpenCV functions: https://github.com/opencv/opencv/blob/4.5.0/modules/python/s...
As to testing this, on Linux I'd run `atop` to see if your program is using all available CPUs.