On a quick search of PHP skills wanted on LinkedIn jobs I found the following large companies looking for it:
Apple,
Cloudflare,
Vimeo,
Box,
Slack,
Tesla,
Etsy,
Wayfair,
Shopify,
Facebook,
Etc
Clearly WordPress and Magento based businesses. Add in Facebook, Weebly/Square, and you realize that PHP probably drives more page views and powers more domain named sites than any other.