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That was in 2008.

"Joe Biden and his wife donated just $70,000 to charity in the two decades leading up to 2017, per their tax returns. But when their earnings skyrocketed in 2017, so did their giving. That year they handed more than $1 million, or about 9% of their income" (including $250K to their own foundations) (still pretty low since he and his surviving children got stinking rich after the Vice Presidency and is quite old)

-Forbes