OMG yes! Andy Pavlo is such a good teacher. I watched his entire lecture series, and it really helped me prepare for an interview. I couldn't recommend his MOOC enough if you really want to know how a database works. I just wish that the homework assignments were available to the public.
Otherwise there is surprisingly a lack of information about architecting databases online and you have to go to the source code of SQLite and PostgreSQL. I suspect this is because databases are some of the most complex systems in computer science and involve many trade secrets.