If you were a blackhat, burning a 0-day at DEFCON would be a huge waste. You probably wouldn't get anything interesting, and chances are someone would catch it.
Nope, you definitely do not. It would definitely get the attention of some vulnerability development types! But there are also more professional - if occasionally less fun - ways to go about that.
If memory serves, the "open" network has seen novel attacks used in years past. But not many.