Any exposure, intentional or accidental, of PII to a non-authorised person is a GDPR violation. An email address is PII as it's unique to that person.
Consider the Ashley Madison breach - there were websites that let you search for an email address and see if it was included. Even without the name or address of the person it was sufficient PII to cause damages (however 'deserved').
On public websites I would agree, but all our mail clients have auto-completion. So would we need to turn that off? Would probably disable half the company.
I don't know who Ashley Madison is but that sounds far beyond sensible protection. Given, auto-completion is restricted to employees plus some locally saved contacts. It is just the standard outlook-exchange setup.
Consider the Ashley Madison breach - there were websites that let you search for an email address and see if it was included. Even without the name or address of the person it was sufficient PII to cause damages (however 'deserved').