For gears in general PLA is fine. If they have a lot of friction they will heat up and that’s where the PLA could fail. But PETG is very easy to print with! You’d need to adjust nozzle and bed temp but it prints very nicely. :)
PLA is fine to start with though. If you see failures you can switch.
I’ve seen fiberglass reinforced nylon gears used with success in commercial injection molded gearboxes. It can definitely help by increasing gear stiffness.
However 3D printing with fiberglass causes rapid nozzle wear, and recently people are saying that fiberglass reinforced 3D printing filaments represent a human hazard.
Since I’ve managed to get my gears to work without reinforcement, I’ve not tried it.
One thing I do with printed gears is make the gear teeth much larger than would be strictly needed in an injection molded solution. This lets me deal with reduced material performance compared to injection molding.
Also have some ideas that includes some motorised parts with gears. Do you think PLA is a bad choice for this?