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by pmahoney
2376 days ago
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The article states the process was discovered > while investigating the crystallization rates of metal, Czochralski dipped his pen into molten tin instead of an inkwell. That caused a tin filament to form on the pen’s tip And later, describes the process for silicon > Once the silicon melted, he placed a small piece of polycrystalline material—a seed crystal It seems then, that the seed crystal is not anything special. A typical piece of metal (such as a the pen tip) is made of up multiple single-crystal "grains" with non-crystalline "grain boundaries" between them; this is a polycrystalline material. The question then is, why does only a single crystal form, rather than multiple crystal filaments oriented at different directions according to whichever grain contacted the starting point of the filament... |
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The silicon wants to be in the lowest energy state and it does so by forming a face centered cubic crystal (diamond structure). The formation of crystals depends on the cooling rate. If matter cools to fast, it can't form a crystal structure.