I'm confused; I'm pretty sure resigning is an act done by the individual, at least supposedly voluntarily, and a quick dictionary check seems to bear that out. Are we just using this as a euphemism, or is there another definition that I needed to learn?
At higher levels of governance (both corporate and governmental) it's customary to not fire people. The way corporate entities/governments get around this is by asking for some one's resignation, with the implication that if it isn't given, the next step will be to forcibly fire that person. There are a lot of social and legal reasons for this, but it mostly boils down to the negative connotations that come with firing someone; it's a way of avoiding shame/saving face for both parties. The person 'being asked to leave' is spared the indignity of being fired, and the institution doesn't have the albatross of 'one of our key leaders fucked up so badly we had to boot them to the curb' hanging around their necks.
You're correct in the definition of 'resigning'. However, there are many cases (and this seems to be one) where people are pushed into resigning against their will. People will still resign, whether out of a sense of honour, or due to the alternative being a prolonged process which will end in the same outcome (being out of a job).
I'm familiar with "asked to resign"; I was asking about the form "they resigned him", which I have not encountered before and which moves it from generally understood euphemism to utterly transparent word replacement.