As far as I can tell in XYZ black is (0,0,0) and the only sRGB value that maps to that is (0,0,0)
If sRGB (1,1,1) is XYZ (1,1,1), then sRGB (0,0,0) is XYZ (0.0025,0.0025,0.0025).
Or if you are using absolute XYZ values, sRGB (0,0,0) is XYZ (0.1901,0.2,0.2178).
If sRGB (1,1,1) is XYZ (1,1,1), then sRGB (0,0,0) is XYZ (0.0025,0.0025,0.0025).
Or if you are using absolute XYZ values, sRGB (0,0,0) is XYZ (0.1901,0.2,0.2178).