No known material could support a tower that tall (towers need compressive strength; elevators need tensile strength). It would need to rely on 'active support' or 'dynamic structures', like a space fountain ( http://www.orbitalvector.com/Orbital%20Travel/Space%20Founta... )
A friend of mine who studies engineering told me that masonry has infinite compressive strength meaning, in theory, it's possible to build monumental structures out of stone.